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Allylpalladium(II) chloride dimer

英文名：Allylpalladium(II) chloride dimer

CAS号：12012-95-2
- 分子式：C6H10Cl2Pd2
  
  外观：
  
  储存：
- 分子量：365.85
  
  质量指标：>98%
  
  CAS：12012-95-2
图谱：

SDS SPEC 核磁

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction.

It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium.

It acts as a precatalyst for asymmetric and cross-coupling catalysis.

Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines.

It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts.

In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta³-allyl chloride complex,
which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

Nakayama, Y.; Yokoyama, N.; Nara, H.; Kobayashi, T.; Fujiwhara, M.
An Efficient Synthesis of N-(Hetero)arylcarbazoles: Palladium-Catalyzed Coupling Reaction between (Hetero)aryl Chlorides and N-Carbazolylmagnesium Chloride.
Adv. Synth. Catal. 2015, 357 (10), 2322-2330.

Chan, K. S. L.; Fu, H. Y.; Yu, J. Q.
Palladium(II)-Catalyzed Highly Enantioselective C-H Arylation of Cyclopropylmethylamines.
J. Am. Chem. Soc. 2015, 137 (5), 2042-2046.

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